TY - JOUR
T1 - Catalytic Palladium-Based and Iron-Based Membrane Reactors
T2 - Novel Strategies of Synthesis
AU - Pinos-Vélez, Verónica
AU - Di Luca, Carla
AU - Crivoi, Dana G.
AU - Medina, Francisco
AU - Dafinov, Anton
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/11/26
Y1 - 2019/11/26
N2 - Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.
AB - Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.
UR - https://www.scopus.com/pages/publications/85075593731
U2 - 10.1021/acsomega.9b02706
DO - 10.1021/acsomega.9b02706
M3 - Artículo
AN - SCOPUS:85075593731
SN - 2470-1343
VL - 4
SP - 19818
EP - 19828
JO - ACS Omega
JF - ACS Omega
IS - 22
ER -